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Metallic photocathodes

These photocathodes are, in first analysis, very attractive for our applications because they accept very high electric fields, higher than 100 MV/m, their relaxation time is very short, of the order of some femtosecondes [ 1 ] and their lifetime is long. However quantum efficiency is low, in the best of cases, with special treatments, QE is at most of the order of some 10-4 electrons by incident photon at 266 nm. The table below reports the main performances of metallic photocathodes measured in different laboratories. Except other specification QE's measurements were realized between 5 and 10 MV/m.

The best performances were obtained with a special surface treatment (see [2] for example). Unfortunately, these performances degrade as the surface contaminates in the RF gun. The lifetime does not exceed few days; however, it is generally possible to restore the initial properties. Furthermore, the low QE of these cathodes implies a strong laser power density at the surface. From a certain threshold there is an "explosive" emission which produces a plasma, then a huge electron production after the end of the laser pulse. For the copper and at 266 nm, this threshold is about 1GW/cm2 (12 mJ/cm2 in 10 ps) [3], for the magnesium it is about half, 400 MW/cm2 [ 4 ] .

QE of some metals

l [nm]

193

213/209

248

266/262

308

355

fs

Ref.

E [eV]

6.4

5.8 / 5.9

5

4.7

4

3.5

eV

 

Al

 

8.4*10-4

 

3.2*10-5

 

3.4*10-7

4.3

[5]

Ag (a)

 

 

 

2*10-5

 

 

4.3

[2]

Au (a)

 

 

 

4.7*10-5

 

 

5.1

[2]

Au

 

4*10-4

 

1.310-5

 

 

5.1

[5]

Ca

 

 

4*10-5

 

 

 

2.9

[4]

Cu

2.0*10-4

1.5*10-4

 

2.2*10-6

1.6*10-7

8*10-9

4.6

[5]

Cu (b)

1.5*10-3

4.2*10-4

 

 

 

 

4.6

[5]

Cu (a)

 

 

 

1.4*10-4

 

 

4.6

[2]

Mg

 

 

 

5.1*10-5

 

 

3.7

[5]

Mg (c)

 

 

 

2.7*10-4

 

 

3.7

[5]

Mg (d)

 

 

 

5*10-4

 

 

3.7

[6]

Mo

 

 

 

<7*10-7

 

 

4.6

[5]

Nb

4.5*10-4

 

3.2*10-6

 

 

 

4.3

[7]

Ni (a)

 

 

 

2.5 10-5

 

 

5.2

[2]

Pd (a)

 

 

 

1.2*10-5

 

 

5.1

[2]

Ac 316 LN

 

9*10-5

 

1.6*10-6

 

 

?

[5]

Sm

 

 

 

 

1.6*10-6

 

2.7

[5]

Sm (a)

 

 

 

7.3*10-4

 

 

2.7

[2]

Ta (a)

 

 

 

10-5

 

 

4.3

[2]

Tb (a)

 

 

 

2.3*10-4

 

 

3

[2]

W (111)(e)

 

 

 

 

 

2*10-5

4.5

[8]

WK+ (b), (f)

 

 

 

 

1.2*10-5

 

2.8

[5]

Y

 

 

 

5*10-4

 

 

3.1

[2]

Y

 

 

 

2.7*10-6

1.1*10-6

 

3.1

[5]

Y (b)

 

 

 

1.8*10-4

 

 

3.1

[5]

Y (a)

 

 

 

5*10-4

 

 

3.1

[2]

Zn (a)

 

 

 

1.4*10-5

 

 

4.3

[2]

Zr (a)

 

 

 

10-5

 

 

4.1

[2]

fs = work function from [9].

(a) = Surface preparation and activation under vacuum, from [2].

(b) = Cleaning by Argon ion bombardment [10]

(c) = Used in the CTF RF gun at 100 MV/m

(d) = ATF (BNL) measurements at 70 MV/m without surface treatment

(e) = Photoemission assisted by high electric field, E = 3 GV/m

(f) = Potassium ions implanted in tungsten substratum (150 keV implantation energy,  ion density 1.3x1017 ions / cm2 at the surface [11])

 

References :

[ 1]

W.E. Spicer and A. Herrera-Gomez,  Modern Theory and Applications of Photocathodes, Proceedings of International Symposium on Optics, Imaging and Instrumentation, San Diego, CA, July 1993

[ 2]

T. Srinivasan-Rao, J. Fischer, and T. Tsang, Photoemission studies on metals using picosecond ultraviolet laser pulses, Jour. of App. Physics, vol. 69 No 5, 1 March 1991

[3]

X.J. Wang, T. Tsang, H. Kirk, T. Srinivasav-Rao, J. Fischer, K. Batchelor, R.C. Fernow, P. Russel, Intense Electron Emission Due to Picoseconde Laser-Produced Plasma in High Gradient Electric Fields, Submitted to Journal of Applied Physics, BNL 45031, January, 1992.

[4]

P. Schoessow, E. Chojnacki, G. Cox, W. Gai, C. Ho, R. Konecny, J. Power, M. Rosing, J. Simpson, N. Barrow, M. Conde, The Argonne Wakefield Accelerator High Current Photocathode Gun and Drive Linac,
ANL-HEP-CP-95-34

[5]

E. Chevallay, J. Durand, S. Hutchins, G. Suberlucq, M. Wurgel, Photocathodes tested in the dc gun of the CERN photoemission laboratory, NIM A 340 (1994)

[6]

X.J. Wang, T. Srinivasan-Rao, K. Batchelor, I. Ben-Zvi, and J. Fischer,  Photoelectrons Beam Measurement from a Magnesium Cathode in a RF Electron Gun, proceedings of LINAC 1994.

[7]

L.N. Hand, U. Happeck, Photoelectric Quantum Efficiency of Niobium for l = 193 nm and l = 248 nm, SRF 95030103

[8]

Y. Gao and R. Reifenberger, Yield of photofield emitted electrons from tungsten, Physical Review B, Third series, vol. 35 No 16, 1 June 1987

[9]

H.B. Michaelson, The work function of the elements and its periodicity, Journal of Applied Physics, vol. 48 No11, November 1977

[10]

M. Wurgel, Nettoyage ionique sous vide des Photocathodes, PS/LP Note Technique No 91-03, janvier 1991

[11]

J.P. Girardeau-Montaut et A. Pérez, private communication, Claude Bernard university, Lyon (F)